ISO 20596-2:2021

Current Revision
Water quality - Determination of cyclic volatile methylsiloxanes in water - Part 2: Method using liquid-liquid extraction with gas chromatography-mass spectrometry (GC-MS)

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ISO 20596-2:2021

Water quality - Determination of cyclic volatile methylsiloxanes in water - Part 2: Method using liquid-liquid extraction with gas chromatography-mass spectrometry (GC-MS)

PUBLISH DATE 2021
ISO 20596-2:2021

This document specifies a method for the determination of certain cyclic volatile methylsiloxanes (cVMS) in environmental water samples with low density polyethylene (LDPE) as a preservative and subsequent liquid-liquid extraction with hexane containing 13C-labeled cVMS as internal standards.

The extract is then analysed by gas chromatography-mass spectrometry (GC-MS).

NOTE: Using the 13C-labeled, chemically identical substances as internal standards with the same properties as the corresponding analytes, minimizes possible substance-specific discrimination in calibrations.

Since these substances are least soluble in water, they are introduced via the extraction solvent hexane into the system.

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