ISO 2613-2:2023

Current Revision
Analysis of natural gas - Silicon content of biomethane - Part 2: Determination of siloxane content by gas chromatography with ion mobility spectrometry

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ISO 2613-2:2023

Analysis of natural gas - Silicon content of biomethane - Part 2: Determination of siloxane content by gas chromatography with ion mobility spectrometry

PUBLISH DATE 2023
ISO 2613-2:2023

This document describes a gas chromatography โ€“ ion mobility spectroscopy (GC-IMS) method for the determination of the concentration of siloxanes in biomethane.

The method is applicable to the following siloxanes:

  • hexamethyldisiloxane (L2);
  • octamethyltrisiloxane (L3);
  • decamethyltetrasiloxane (L4);
  • dodecamethylpentasiloxane (L5);
  • hexamethylcyclotrisiloxane (D3);
  • octamethylcyclotetrasiloxane (D4);
  • decamethylcyclopentasiloxane (D5);
  • dodecamethylcyclohexasiloxane (D6).

This document describes suitable calibration and measurement strategies to quantify siloxanes in (bio)methane around and above the 0,3 mg m-3 (14 ยตmol mol-1) level and applies to analyses within absolute pressure ranges of 1 bar โ€“ 2 bar, temperatures of 0 ยฐC โ€“ 40 ยฐC, and relative humidity < 90 %.

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