ISO 6923:2023

Current Revision
Paints and varnishes - Determination of monomeric diisocyanate content in coating materials and similar products using high performance liquid chromatography with ultraviolet detection (HPLC-UV)

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ISO 6923:2023

Paints and varnishes - Determination of monomeric diisocyanate content in coating materials and similar products using high performance liquid chromatography with ultraviolet detection (HPLC-UV)

PUBLISH DATE 2023
ISO 6923:2023

This document specifies a method for the quantitative determination of monomeric diisocyanate content in coating materials, adhesives and other liquid or pasty materials.

This method is suitable for the quantification of the following monomeric diisocyanates:

  • methylene diphenyl diisocyanate (MDI, 2,4’-MDI and 4,4’-MDI),
  • toluene diisocyanate (TDI, 2,6-TDI, 2,4-TDI),
  • (cis/trans) isophorone diisocyanate (IPDI)
  • hexamethylene diisocyanate (HDI,1,6-HDI)

in various matrices for concentrations ranging from 0,01 % to 2,0 % mass fraction. For higher concentrations, a suitable dilution before the derivatization with p-nitrobenzyl-N-propylamine (PNBPA) is performed.

The measurements are carried out using ultra high performance liquid chromatography (UHPLC) with a multiple wavelength detector.

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